Вестник МГТУ. 2020, Т. 23, № 1.

Conclusion As a result of this study of 15 small lakes in the southern part of the Republic of Karelia and core samples of the sediments from these lakes, the average content of 42 chemical elements, including heavy metals, was estimated, which can be used as background values for the study area. Our analysis of the obtained background values showed that the deeper (pre-industrial) sediment layers in the lakes are significantly depleted in all elements compared to the continental crust. An exception is Mo, whose ores and ore occurrences are widespread in the south of Karelia. In addition, it was found that the averaged concentrations of rare-earth elements in the sediments of lakes in the south of Karelia have a similar distribution pattern with the trend observed in the upper continental crust. Enrichment in light rare-earth elements and a negative Eu anomaly were observed. A comparative analysis of the obtained background levels of Pb, Cd, Cu, Ni, Zn, Cr and similar data from the Murmansk Region and Scandinavian countries highlighted the compared values that are similar. In addition, similar values were obtained when comparing the average concentrations of chemical elements in the lake and river and stream sediments in the south of Karelia. A minor difference was found only for Sr, V, and Cr that to a large extent gravitate toward the terrigenous fraction of the sediments, which is better represented in stream sediments. Our findings can form the basis for an extensive study of the background concentrations of chemical elements in sediments throughout the Republic of Karelia, including the identification of the background values of elements for different lithological types of sediment (sapropels, diatomites, mineral, ferruginous, and carbonate sediments). Acknowledgments The author expresses gratitude to A. S. Medvedev, D. G. Novitsky, E. V. Siroezhko, M. A. Medvedev, and T. S. Shelekhova, who helped between 2016 and 2018 with the fieldwork, including sampling of lake sediments, A. S. Paramonov, M. V. Ekhova, and V. L. Utitsina for the performance of analytical studies, S. A. Svetov, and V. A. Dauvalter for valuable advice and support while writing this paper. The research is supported by state project No AAAA-A18-118020690231-1 (analysis of the composition of Karelian lake sediments), the grant of the President of the Russian Federation, project No MK-462.2019 (assessment of the age of lake sediments), and project of the Russian Science Foundation No. 19-77-10007 (comparison of metal contents in sediments of lakes from Karelia and Murmansk region). References Bartnicki, J. 1994. An Eulerian model for atmospheric transport of heavy metals over Europe: Model description and preliminary results. Water Air & Soil Pollution, 75(3-4), pp. 227-263. DOI: https://doi.org/10.1007/ BF00482939. Belkina, N. A., Vapirov, V. V., EfTemenko, N. A., Romanova, T. N. 2012. On the question of the ways of natural migration of copper to Lake Onega. Principles o f Ecology, 1, pp. 25-28. DOI: https://doi.org/10.15393/ j1.art.2012.483. (In Russ.) Catalogue of lakes and rivers of Karelia. 2001. Eds. N. N. Filatov, А. V. Litvinenko. Petrozavodsk. (In Russ.) Dauvalter, V. A. 2012. Geoecology of lake bottoms sediments. Murmansk. (In Russ.) Dauvalter, V. A., Kashulin, N. A. 2014. Geoecology of the lakes of the Murmansk region. Murmansk. (In Russ.) Dauvalter, V., Kashulin, N. 2010. Chalcophile elements (Hg, Cd, Pb, As) in Lake Umbozero, Murmansk Province. Water Resources, 37(4), pp. 497-512. DOI: https://doi.org/10.1134/s0097807810040093. Dauvalter, V., Kashulin, V., Sandimirov, S., Terentjev, P. et al. 2011. Chemical composition of lake sediments along a pollution gradient in a Subarctic watercourse. Journal o fEnvironmental Science and Health, Part A: Toxic/Hazardous, 46(9), pp. 1020-1033. DOI: https://doi.org/10.1080/10934529.2011.584503. Demidov, I. N., Shelekhova, T. S. 2006. Diatomites of Karelia (features of formation, distribution, prospects of use). Petrozavodsk. (In Russ.) Escobar, J., Whitmore, T. J., Kamenov, G. D., Riedinger-Whitmore, M. A. 2013. Isotope record of anthropogenic lead pollution in lake sediments of Florida, USA. Journal o f Paleolimnology, 49(2), pp. 237-252. DOI: https://doi.org/10.1007/s10933-012-9671-9. Geochemical mapping of the north of the European territory of Russia within the framework of the international program "Ecogeochemistry of the Barents Region" and the leading stage of compiling the geochemical foundations of the third generation State Geological Map-1000 on sheets P-35.36. 2004. Report. Saint Petersburg. (In Russ.) Hakanson, L. 1984. Sediment sampling in different aquatic environments: Statistical aspects. Water Resources Research, 20(1), pp. 41-46. DOI: https://doi.org/10.1029/wr020i001p00041. Hosono, T., Alvarez, K., Kuwae, M. 2016. Lead isotope ratios in six lake sediment cores from Japan Archipelago: Historical record of trans-boundary pollution sources. Science o f the Total Environment , 559, pp. 24-37. DOI: https://doi.org/10.1016/j.scitotenv.2016.03.138. Interpretation of geochemical data. 2001. Ed. Е. V. Sklyarov. Moscow. (In Russ.)

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